If the solvent casting involves phase separation , you may expect wide differences. The same is true if you cast semicrystalline polymer films. The amount of residual solvent may also be different.
Please explain phase separation in the polymerization of monomer with the solvent and than again same polymerization of monomer with the other solvent by solvent casting process.
Thanks to Rinkesh ji & Gyorgy sir for your reply.I think here phase separation means, Due to long relaxation time and large scale of polymer molecules, the morphology of phase separation in polymer systems can exhibit many special features such as volume shrinking and phase inversion phenomenon compared with that in small molecule system.