Commercially available. Must be colorless or with a light color. It needs to be soluable in common organic solvents, like toluene, acetone, THF or other.
A typical rubber with low gas permeation which might suit your application is butyl rubber (IIR), but it is of course not, as i expect all other polymers, really impermeable.
To reach (near) impermeability a metal might be used.
All polymers used for food packaging are (or must be) non-toxic and of good barrier properties for oxygen. Polyethyleneterephthalate (PET), for example
Thank you everyone! I think I will use one of the following: PVA, PVDC or PAN. The thing is about O2 diffusion rate through the material and it needs to be extremely low in my case.
@ Dimitri Likhatchev: PET is actually an example of a polymer with not sufficient barrier properties - that is why beer is not very stable in PET bottles.