In our current understanding of the universe based on the second law of thermodynamics, the total entropy of the universe can never remain zero and is always increasing. But let's explore the nuances behind this statement:
Why entropy can't stay zero:
Entropy measures disorder: Entropy can be understood as a measure of disorder or "spread" of energy within a system. Imagine mixing hot and cold coffee; the initially organized state becomes a uniform (disordered) lukewarm state. This change reflects an increase in entropy.
Isolated systems tend to disorder: The second law states that in an isolated system (no energy exchange with the outside), entropy tends to increase over time. This means systems naturally move towards states of higher disorder unless external work is done to maintain order.
Universe as an isolated system: Considering the vastness and presumed lack of significant energy exchange with the outside, the universe can be considered an isolated system. Therefore, its overall entropy cannot stay zero but must constantly increase.
Why entropy always increases:
Energy dispersion: Processes like friction, heat transfer, and chemical reactions lead to energy dispersion and increasing disorder. For example, a burning candle transforms ordered chemical bonds into more dispersed forms of energy like heat and light, increasing entropy.
Irreversible processes: Most natural processes are irreversible, meaning they cannot be perfectly reversed without external energy input. Each irreversible process contributes to the rise in entropy.
Statistically likely: Systems with high disorder are exponentially more likely than highly ordered states. Over time, systems naturally "drift" towards more probable (disordered) states, leading to the persistent increase in entropy.
Exceptions and special cases:
Open systems: In open systems with external energy input, local pockets of order can be created (e.g., living organisms), but the overall entropy of the combined system (including the energy source) still increases.
Fluctuations: Tiny, temporary decreases in entropy might occur on microscopic scales due to random fluctuations, but these are insignificant compared to the overall upward trend.
The increasing entropy of the universe suggests a possible ultimate fate of "heat death," where everything reaches a state of maximum disorder with no usable energy, but that's another fascinating topic for another time!
The entropy obeys the law of conservation of energy, acting as a friction force during mechanical motion. If we assume that there is a system with zero entropy, then we can construct a perpetual motion machine