About suitable solvents for poly(vinylidene fluoride), i.e. PVDF, you may find useful to check: https://www.researchgate.net/post/How_can_I_dissolve_PVDF_What_kind_of_solvent_completely_dissolve_PVDF_and_is_not_toxic_I_know_nMP_and_MEK_but_I_dont_want_to_use_anything_toxic