There are two minerals which should be consider when it comes to primary mineral depending on the Eh regime it is halite and pyrite. The first is highly soluble and washed out by supergene processes from primary evaporitic sediments when subjected to humid conditions without anything left as a residue. Accompanying less soluble minerals may be gypsum, anhydrite or celestite. Pyrite is typical of sedimentary environments of Eh
Dear H.G. Dill, thanks a lot for your opinion. Soon I will study its thin section. I will also try to do geochemical analysis of sample(s) of these rocks....once I have these results so I will do interpretation considering your comments.