Recently, we are trying to aluminize a high Cr superalloy at 1000C.
Because of the high Cr(15%) content and activity inside the superalloy, the Cr formed a Cr-rich layer beneath the coating, like a barrier suppressing the Nickel from diffusion outside, and seem to stop the aluminum from diffusing inside as well.
It is probably due to the low activity of Ni and Al in a Cr-rich Ni-Al-Cr system. Does anybody have any papers or an activity diagram that can solve my problem?
Any ideas are welcome.