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As we know thermal fluctuation is always present in any system at non zero temperature. And in magnetic systems when the exchange interactions dominate the thermal fluctuation a classical phase...
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Generally with increasing pressure, the XRD peaks are get shifted towards higher theta values. But there is always the FWHM of the peaks gets increases with pressure. Is the non hydrostatic...
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Like Gruneisen parameter explains the effects of phonon vibration frequency with volume, is there any parameter which could explain the effect of volume on the d-d electronic absorption spectra...
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