Why self-assembled Pt(II) complexes show emissive properties, but Pd(II) don't; even though Pt is heavier metal than Pd.

Generally, due to spin-orbital coupling, the metallocages based on heavy metals should not show emissive properties. But, many Pt(II) based metallocages show emissive properties and at the same...

03 July 2017 2,080 3 View