Joseph Sloop

2 Questions 26 Answers 0 Followers

Questions related from Joseph Sloop

What is the best ab initio/computational method to model transition structures for a pyrazole equilibrium?

Diketone and aryl hydrazine condensation reactions often lead to a mixture of regioisomeric pyrazoles. Preliminary calculations show 2-4 kcal/mol differences in the pyrazole energies.

28 January 2015 1,262 1 View

Besides acetonitrile, what other suitable solvents that are not polar, protic solvents can be used to solvate Selectfluor effectively?

I have been attempting to fluorinate a ketone species that apparently is unreactive toward Selectfluor in acetonitrile.

27 January 2013 1,926 13 View