A sample of Polyethylene has an average degree of polymerisation of 1200. What is the coiled length and the extended length of an average molecule given the bond length is 0.154nm and the bond angle between three adjacent C atoms is near 109.5°.
Dear Michael Fitzpatrick, perfectly extended PE chains assume a zig-zag arrengement, where the length is the sumation of the triangles bases lengths (easily obtained through the data you mentionned). For the coiled arrengement, mainy approaches and theories are devoted to that. Please read the attached files. My Regards
Dear Michael Fitzpatrick, perfectly extended PE chains assume a zig-zag arrengement, where the length is the sumation of the triangles bases lengths (easily obtained through the data you mentionned). For the coiled arrengement, mainy approaches and theories are devoted to that. Please read the attached files. My Regards
A polymer chain is a concatenated sequence of monomers. It pervades spatial dimensions on the size scale of tens of nanometers. A polymer chain is built-up from hundreds to many hundreds of thousands of monomer units. Polymer chains are fractal objects whose dimensionality is determined by interactions between the monomeric units and solvent molecules. Through molecular imaging, one can measure both the persistence length and the fractal dimension of single molecules in various environments.
The kinetic chain length of a polymer is the average number of monomers added to a growing chain during chain-growth.
The contour length of a polymer chain is its length at maximum physically possible extension. Contour length is equal to the product of the number of segments of polymer molecule(n) and its length. The chain contour length is obtained by dividing the Molar Weight of a polymer by the Molar weight of its monomer unit and multiplying this ratio with the length of the monomer unit.
Displacement length of a coiled polymer is the distance between one end of the polymer chain and the other for a coiled polymer
As the contour length of a polymer is the distance between one end of the polymer chain and the other when the polymer is stretched out, so it could be considered the maximum possible displacement length.