It is possible to synthesis Ru(II) complexes from Ru(III) precursors?

09 September 2016 1 5K Report

Can you correlate the literature reports?

It is possible if the medium used can have a reducing effect on the metal oxidation state. Ru(II) starting materials such as [RuHCl(CO)(PPh3)3] or [RuHCl(CO)(AsPh3)3] or various Ru(II)-are startings are in fact prepared from RuCl3 where ruthenium has Ru(III) oxidation state.

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Chemistry, Organic
Synthesis

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