I think that you have to modified the electrode with something

I agree with B.Y. Xia

I think just by adsorption it could be easy the immobilization of colloidal gold onto carbone electrode. Good luck

Depend on which carbon. Adsorption should be OK for an PG electrode. But if you take a GC electrode you'll likely have to modify it. Maybe a C12 thiol should work. The C12 chains adsorb very well on GC surface.

you can make an electrodeposition of a conducting polymer on carbon electrode with colloid of gold particles in solution, see article of HABELHAMES in synthetic metals, it' easy. good luck

you can disperse Au particles with PFSA, the suspension will adhere on carbon electrode easily. u also can find some articles about low PEMFc

The best adsorption or immobilization can be achieved by determining the pzc of colloidal gold for the given electrode in the given medium. Then you apply the potential at which the Au particles show high adsorption. Good luck.

The best adsorption or immobilization can be achieved by determining the pzc of colloidal gold for the given electrode in the given medium. Then you apply the potential at which the Au particles show high adsorption. You can refer the article published by Malliya kumaravel in electrochimica acta.Good luck.

Carbon electrodes are known to have oxygen containing functionalities and these functionalities can acts as binding sites and allow the colloidal gold particles to grow with out any external aid. so you can do simple drop casting of known amount of colloidal gold and dry it completely otherwise you dont have consistancy. please remember while asking anythings you please try give the perticular purpose where you are going to apply so it is preety good for us to give suggestions. All the very best. Any more questions, highly appreciated.

If we coat in powdered form we cannot have uniform distribution of particles on the surface of carbon, in addition to this most of the purposes require finite thickness of the modifier layer on the suraface. this is not possible when we modify the suraface with powder but it can be easily achievable via drop casting because the nature of casting and the evoparation of solvent play very important role..

You can dip a porous carbon electrode in an aqueous solution of Chloroauric Acid (0.01%p/V), and then place this wet electrode on the boiling citrate solution (ca. 100 ºC). You will produce a colloidal gold "in situ" on the porous electrode using the Frens method.

There are innumerable techniques available in the literature. Mostly, E-beam, Solution based techniques are prominent. People have done extensive work on this subject. Also, Electro deposition of conducting materials on carbon electrodes and other important information is available and please refer following papers:

1) " Gold nano particle based electrochemical sensors" Electrochemica Acta, vol 53, issue 19, 1 August 2008, pages 5848-5866; by Jose M. Pin garron et al, 2) " A comparison of different types of Gold -Carbon composite electrode for detection of arsenic (III) by Andrew O. simm et al, Analytical & Bio analytical chemistry Vol 381, No 4, 979-985 .

Hope, this will solve your problem.

Fallyn W. Campbell & Richard G. Compton.

The use of nanoparticles in electroanalysis: an updated review.

Anal Bioanal Chem (2010) 396:241–259

Regards

Please check our paper in Electrochimica Acta 2011; Electrochimica Acta 56 (2011) 7092– 7096

As raghu suggested drop cast method should work.....

It worked for me unless you are using it for harsh conditions..

Then its fine Lakshman. you should optimize the thickness of the colloidal layer for your application.

there are two ways; 1) -300mV chronoamperometric application in the solution for 5 min. 2) activation of carbon electrode at 1,75 V for 2 min. then dropped gold colloid solution on electrode surface and wain until dry you must purge nitrogen gas in gold solution in everytwo ways.

You can try LBL