I have synthesized one pi-conjugated aromatic molecule, in which a single proton (double bond connected, non-coupled proton) shows the singlet signal (Peak) at two different ppm values. It shows one signal at 8 ppm and another one at 10.4 ppm. At a lower concentration of sample 8 ppm signal integration is high (0.8 proton) and 10.4 ppm signal integration is low (0.2 proton). I would like to know
1. Why this proton is showing two signals at two different ppms.
2. Why this proton signal integration is changing with varying sample concentrations.