It is possible if your Matlab is not older then 2009. I would suggest to define your own class (data type). It has its limitations and might be a little bit slower but if you really need zero indexing you can do it (basically you could do any indexing with that). Please read the tutorials about Object Orientated Programming.
I attached a class definition that basically does what you want. Just include it into your Matlab search path, then you then can try the following:
Please bear with me, because of time I did not comment any of the code. Let me know whether you have any question.