well, the question is not really clear. Even though, polyesterification reactions are acid catalyzed. Other catalysts include triphenylphosphine and derivatives, picryl chloride, DBU, and others. Regards
It depends on your reactants. Generally, Zn, Co, Mn acetates or tin organics such as di-n-butyl tin diacetate are recommended. Further information maybe obtained from Ullmann's Encyclopedia of technical chemistry.
the best catalyst for production different kind of polyols are louis acids and between these in lab scale is para-tuluene sulponic acid and in industrial level Titanate catalyst such as tetrbutyl isopropyl titanate are best